个人信息

姓  名: 辛颢 性  別: 导师类型: 博士生导师
技术职称: 教授 电子邮箱: iamhxin@njupt.edu.cn
学术型博士招生学科: (080300)光学工程
学术型硕士招生学科: (083100)生物医学工程,(070300)化学
专业型硕士招生类别(领域): (085400)电子信息
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个人简介:

2003年毕业于北京大学化学与分子工程学院,获无机化学博士学位。2003年到2006年先后以JST CREST JSPS研究员的身份在日本物质材料研究机构和日本北路先端科学技术大学院大学从事无机发光材料方面的研究。20061220155月在美国华盛顿大学从事有机和铜锌锡硫薄膜太阳能电池方面的研究。20156月回南京邮电大学工作。现为南京邮电大学南京邮电大学有机电子与信息显示国家重点实验室、化学与生命科学学院教授,博士生导师。研究领域为光电功能材料及器件,包括铜锌锡硫(CZTS),铜铟镓硒(CIGS)和钙钛矿太阳能电池。在Nature Energy, Journal of the American Chemical Society, Energy and Environmental Science, Advanced Energy Materials, Advanced Functional Materials, Nano Energy, ACS Nano, Chemistry of Materials, Journal of Materials Chemistry, SCIENCE CHINA Materials等国内外知名学术期刊发表SCI论文80多篇,引用次数超过5000次。获授权国际专利两项,日本专利两项,中国专利十余项。主持科技部重点研发项目(课题)两项,国自基金面上项目两项。

















研究领域:

研究领域涉及光电功能材料及其应用,目前主要研究领域为薄膜太阳能电池,包括三个研究方向:(1)铜铟镓硒(CIGS)薄膜太阳能电池。与传统(已经商业化)真空法制备CIGS材料不同,本课题组通过溶液法制备CIGS薄膜材料,通过控制溶液中前驱体化合物的组成和薄膜生长来调控薄膜光电性质和光伏性能,探索实现低成本大规模制备CIGS的途径。在二甲基甲酰胺(DMF),水和甲基吡咯烷酮(NMP)三个溶液体系的研究处于世界领先地位。(2)铜锌锡硫(CZTS)薄膜太阳能电池。CZTSCIGS具有相似的晶体结构和理论高效率,但CZTS以储量丰富元素为组元,因此更有希望实现低成本高效光伏技术。本课题组通过溶液法制备CZTS薄膜材料,通过控制溶液化学反应、掺杂、薄膜生长、异质结优化等手段探索制约CZTS效率的因素及其作用机制,取得了一系列创新成果。2020年创造铜锌锡硫中国效率;2021电池经美国可再生能源国家实验室(NREL)认证,效率达到13.0%,该效率打破了IBM公司保持8年之久的12.6%的记录,创造了铜锌锡硫新的世界记录效率, 被NREL发表的电池效率表收录;首次制备CZTS电池组件并于2024年经NREL认证效率达到10.1%,创造了该类电池第一个组件世界记录效率,被马丁格林电池效率表收录。(3)钙钛矿薄膜太阳能电池。 包括钙钛矿吸光层材料的制备,界面性质调控,半透明电池,以及以钙钛矿电池为顶电池的叠层电池研究。

















科研项目:

1)科技部重点研发计划,“新型硫族化合物前驱体设计和高质量薄膜沉积制备”,编号2024YFB4205000 300.00万元,202412月至 2027 11月,项目负责人,在研。

1)科技部重点研发计划政府间国际科技创新合作重点专项,“制约铜锌锡硫太阳能电池性能的关键缺陷及其作用机制研究”,编号2019YFE0118100 202012月至 2023 11月,259.00万元,项目负责人,结题。

2)国家自然科学基金,DMF溶液法制备高效铜铟镓硒薄膜太阳能电池:富铜吸光材料的碱金属离子掺 杂和表面后处理研究,编号2207515020211-202412月,63万元,项目负责人,结题。











代表性学术成果:

1.       Chunxu Xiang, Mingjun Yuan1, Chuanan Ding, Yuanyuan Zheng, Yize Li, Xiaole Hu, Jie Zhang, Xinyu Li, Chengfeng Ma, Shaoying Wang*, Weibo Yan, Chunlei Yang, Wei Huang*, Hao Xin* Solution-Processed Kesterite Solar Module with 10.1% Certified Efficiency, Nature Energy, 2025, DOI:10.1038/s41560-025-01860-3.

2.       Licheng Lou, jinlin Wang, Yuan Li, Kang Yin, Xiao Xu, Bowen zhang, Menghan jiao, shudan chen, Tan Guo, jingchen Wang, Yiming Li, jiangjian shi*, Huijue Wu, Ruijuan Xiao, Hao Xin*, Yanhong Luo*, Dongmei Li, Qingbo Meng* Multi-interface engineering for all-solution-processed kesterite solar cells, Joule, 2025, DOI: 10.1016/j.joule.2025.102091.

3.       Aoqi Xu, Xinyu Li, Hongkun Liu, Chunxu Xiang, Chengfeng Ma, Yize Li,  Xiangyu Pan, Weibo Yan, Shaoying Wang, Wei Huang, Hao Xin* Over 10% Efficiency Pure Sulfide Kesterite Solar Cells on Transparent Electrode with Cd-Ag Co-Alloying, Small, 2025, 21, 2407075.

4.       Hongkun Liu, Yize Li, Aoqi Xu, Xinyu Li, Chunxu Xiang, Sifan Zhou, Shaoying Wang*, Weibo Yan*, Hao Xin*, 8.36% Efficient CZTS Solar Cells on Transparent Electrode via Solution Processing, Solar RRL. 2024, 8, 2400588.

5.       Yuanyuan Zheng, Chunxu Xiang, Yuancai Gong, Yize Li, Shiliang Xiao, Haoyu Guo, Chengfeng Ma, Shaoying Wang*, Weibo Yan*, Wei Huang, Hao Xin*, Effects of cadmium alloying on solution-processed CZTSSe solar cells: morphology, band alignment and efficiency improvement, Sci. China Mater. 2025, 68, 523-530.

6.       Sitong Xiang, Yize Li, Chunxu Xiang, Hongkun Liu, Yuanyuan Zheng, Shaoying Wang*, Weibo Yan* and Hao Xin*, Improving the performance of kesterite solar cells by solution germanium alloying, Phys. Chem. Chem. Phys., 2024, 26, 20645-20652

7.       Hongzheng Dong, Xiangyu Pan, Yuancai Gong, Mengfan Xue, Pin Wang, SocMan Ho-Kimura, Yingfang Yao, Hao Xin*, Wenjun Luo*, Zhigang Zou, Potential window alignment regulating ion transfer in faradaic junctions for efficient photoelectrocatalysis. Nature Communications, 2023, 14: 7969.

8.       Xinyu Li, Chengfeng Ma, Naiyun Liu, Chunxu Xiang, Shuxia Wei, Weibo Yan, Wei Huang*, Hao Xin*, Back Contact Plasma Treatment Enables 14.5% Efficient Solution-Processed CuIn(S,Se)2 Solar Cells, Advanced Functional Materials, 2023, 2310124.

9.       Lisi Yang, Shuaishuai Shen, Xiang Chen, Huan Wei, Dongdong Xia*, Chaowei Zhao, Ningfang Zhang, Yuanyuan Hu, Weiwei Li, Hao Xin*, Jinsheng Song*, Doped/Undoped A1-A2 Typed Copolymers as ETLs for Highly Efficient Organic Solar Cells, Advanced Functional Materials, 2023, 2303603.

10.    Yage Zhou, Chunxu Xiang, Qi Dai, Sitong Xiang, Ran Li, Yuancai Gong, Qiang Zhu, Weibo Yan, Wei Huang*, Hao Xin*, 11.4% Efficiency Kesterite Solar Cells on Transparent Electrode, Advanced Energy Materials, 2023, 2300253.

11.    Jiazheng Zhou, Xiao Xu, Huijue Wu, Jinlin Wang, Licheng Lou, Kang Yin, Yuancai Gong, Jiangjian Shi, Yanhong Luo, Dongmei Li*, Hao Xin*, Qingbo Meng*, Control of the phase evolution of kesterite by tuning of the selenium partial pressure for solar cells with 13.8% certified efficiency, Nature Energy, 2023, 8, 526–535.

12.    Mingjun Yuan, Chunxu Xiang, Zhen Yan, Hongfei Zhou, Naiyun Liu, Shuxia Wei, Wei Li, Weibo Yan, Chunlei Yang*, Hao Xin*, 4.3% efficient kesterite solar cell modules, Science Bulletin, 2023, 68(14), 1497-1499.

13.    Shuxia Wei, Chengfeng Ma, Xinge Liu, Naiyun Liu, Mingjun Yuan, Kang Xiao, Weibo Yan*, Hao Xin*, A facile synthesis of a copper(i) thiourea sulphate complex and its application for highly efficient chalcopyrite solar cells, 2023, Chemical Communications, 59(65), 9848-9851.

14.    Xiangyu Pan, Xinyu Li, Yuntian Yang, Chunxu Xiang, Aoqi Xu, Hongkun Liu, Weibo Yan, Wei Huang*, Hao Xin*, 12.3% Efficient Low Voc Loss Pure Sulfide Kesterite Solar Cells from DMSO Solution via Cadmium Alloying, Advanced Energy Materials, 2023, 2301780.

15.    Liu Xinge, Ma Chengfeng, Xin Hao*, Ding Liming*, Solution-processed CuIn(S,Se)2 solar cells on transparent electrode offering 9.4% efficiency, Journal of Semiconductors, 2023, 44(8), 080501.

16.    Weibo Yan, Wensheng Yang, Kangjie Zhang, Hui Yu, Yuntian Yang, Hao Fan, Yuanyuan Qi, and Hao Xin*, Enhancing Performance and Stability of Perovskite Solar Cells through Surface Defect Passivation with Organic Bidentate Lewis Bases, ACS Omega, 2022, 7(36), 32383–32392.

17.    Shuaiqi Han, Jingjing Jiang, Xinge Liu, Bingyan Li, Kangjie Zhang, Shasha Hao, Shaotang Yu, Weibo Yan*, Hao Xin*, Chemical-Bath-Deposited Zn(S,O) Buffer Achieves 12.0% Efficient Solution-Processed CIGS Solar Cells, ACS Appl. Energy Mater. 2022, 5(10), 12336–12346.

18.    Yuancai Gong, Qiang Zhu, Bingyan Li, Shanshan Wang, Biwen Duan, Licheng Lou, Chunxu Xiang, Erin Jedlicka, Rajiv Giridharagopal, Yage Zhou, Qi Dai, Weibo Yan, Shiyou Chen*, Qingbo Meng*, Hao Xin*, Elemental de-mixing-induced epitaxial kesterite/CdS interface enabling 13%-efficiency kesterite solar cells, Nature Energy, 2022, 7, 966–977.

19.    Shaotang Yu; Bingyan Li; Jingjing Jiang; Xinge Liu; Shasha Hao; Shuaiqi Han; Weibo Yan*; Hao Xin*, Solution-Processed Chalcopyrite Solar Cells: the Grain Growth Mechanism and the Effects of Cu/In Mole Ratio, Advanced Energy Materials, 2022, 2103644.

20.    Chengfeng Ma; Chunxu Xiang; Xinge Liu; Bingyan Li; Xinyu Li; Shuaiqi Han; Qi Dai; Weibo Yan*; Hao Xin*, Over 12% efficient CuIn(S,Se)2 solar cell with the absorber fabricated from DMF solution by doctor-blading in ambient air, Solar RRL, 2022, 2200150.

21.    Shasha Hao; Shaotang Yu; Xinge Liu; Bingyan Li; Shuaiqi Han; Hao Xin; Weibo Yan*, Wei Huang*, Effect of K Doping on the Performance of Aqueous Solution-Processed Cu(In,Ga)Se2 Solar Cell, Advanced Energy & Sustainability Research, 2022, 2200006.

22.    Jinlin Wang; Jiazheng Zhou; Xiao Xu; Fanqi Meng; Chunxu Xiang; Licheng Lou; Kang Yin; Biwen Duan; Huijue Wu; Jiangjian Shi; Yanhong Luo; Dongmei Li*; Hao Xin*; Qingbo Meng*, Ge-Bidirectional Diffusion to Simultaneously Engineer Back Interface and Bulk Defects in the Absorber for Efficient CZTSSe Solar Cells, Advanced Materials, 2022, 2202858.

23.    Licheng Lou; Yuancai Gong; Jiazheng Zhou; Jinlin Wang; Xiao Xu; Kang Yin; Biwen Duan; Huijue Wu; Jiangjian Shi; Yanhong Luo; Dongmei Li*; Hao Xin*; Qingbo Meng*, A feasible and effective solution-processed PCBM electron extraction layer enabling the high VOC and efficient Cu2ZnSn(S, Se)4 devices, Journal of Energy Chemistry, 2022, 70, 154-161.

24.    Yuancai Gong; Ruichan Qiu; Chuanyou Niu; Junjie Fu; Erin Jedlicka; Rajiv Giridharagopal; Qiang Zhu; Yage Zhou; Weibo Yan;Shaotang Yu; Jingjing Jiang; Sixin Wu*; David S. Ginger*; Wei Huang*; Hao Xin*; Ag Incorporation with Controlled Grain Growth Enables 12.5% Efficient Kesterite Solar Cell with Open Circuit Voltage Reached 64.2% Shockley-Queisser Limit, Advanced Functional Materials, 2021, 2101927.

25.    Yuancai Gong; Yifan Zhang; Qiang Zhu; Yage Zhou; Ruichan Qiu; Chuanyou Niu; Weibo Yan*; Wei Huang; Hao Xin*, Energy & Environmental Science, 2021, 14(4): 2369-2380.

26.    Chuanyou Niu; Yuancai Gong; Ruichan Qiu; Qiang Zhu;Yage Zhou; Shasha Hao;Weibo Yan*; Wei Huang; Hao Xin*, Journal of Materials Chemistry A, 2021, 9 (22) , 12981-12987.

27.    ShaotangYu, JgjingJiang, Shuaiqi Han, Shasha Hao, Qiang Zhu, Yuancai Gong, WeiboYan, Wei Huang, Hao Xin* “Structure engineering of solution-processed precursor films for low temperature fabrication of CuIn(S,Se)2 solar cells”, Solar Energy, 2021, 220, 796-801.

28.    Yuancai Gong; Yifan Zhang; Erin Jedlicka; Rajiv Giridharagopal; James A. Clark; Weibo Yan; Chuanyou Niu; Ruichan Qiu; Jingjing Jiang; Shaotang Yu; Sanping Wu; Hugh W. Hillhouse; David S. Ginger; Wei Huang; Hao Xin*, Science China Materials,2021, 64(5): 1304-1304.

29.    Zilong Wang, Di Lu, Jingjing Jiang, Weibo Yan, Yuancai Gong, Sanping Wu, Yifan Zhang, Wei Huang, and Hao Xin* “In Situ Formation of Ag2MoO4 in a Ag/MoO3 Buffer Layer Enables Highly Efficient Inverted Perovskite Cell for a Tandem Structure”, ACS Applied Energy Materials 2020, 3 (10), 9742-9749.

30.    Chen, J. H.; Tang, C. C.; Guo, S. G.; Wang, Z. L.; He, Z. X.; Hwang, Y.-J.; Yan, W. B.; Xin, H. and Huang W.* “High crystalline small molecule manipulates polymer-fullerene morphology and enables 20% improvement in fill factor and device performance,” Organic Electronics, 2020, 77, 105419.

31.    Jiang, J. J.; Giridharagopal, R.; Jedlicka, E.; Sun, K. W.; Yu, S. T.; Wu, S. P.; Gong, Y. C.; Yan, W. B.; Ginger, D. S.;* Green, M. A.; Hao, X. J.;* Huang, W. and Xin, H.* “Highly Efficient Copper-Rich Chalcopyrite Solar Cells from DMF Molecular Solution” Nano Energy 2020, 69, 104438.

32.    Romanyuk, Y. E.; Haass, S. G.; Giraldo, S.; Placidi, M.; Tiwari, D.; Fermin, D. J.; Hao, X. J.; Xin, H.; Schnabel, T.; Kauk-Kuusik, M.; Pistor, P.; Lie, S.; and Wong, L. H.Doping and alloying of kesterites” Journal of Physics: Energy, 2019, 1, 044004.

33.    Wu, S. P.; Jiang, J. J; Yu, S. T.; Gong, Y. C.; Yan, W. B.; Xin, H.* and Huang, W. “Over 12% efficient low-bandgap CuIn(S,Se)2 solar cells with the absorber processed from aqueous metal complexes solution in air” Nano Energy 2019, 62, 818-822.

34.    Yu, S. T.; Gong, Y. C.; Jiang, J. J; Wu, S. P.; Yan, W. B.*; Li, X. A.; Huang, W. and Xin, H.* “Over 10% Efficient CuIn(S,Se)2 Solar Cells Fabricated From Environmentally Benign Solution in Air” Solar RRL, 2019, 1900052.

35.    Yan, W.; Wang, Z.; Gong, Y.; Guo, S.; Jiang, J.; Chen J.; Tang, C.; Xia, R.; Huang, W.; Xin, H.*Naphthalene-diimide selenophene copolymers as efficient solutionprocessable electron-transporting material for perovskite solar cells” Organic Electronics, 2019, 67, 208-214.

36.    Hao Xin,* Weibo Yan and Samson A. Jenekhe*, Color-Stable White Organic Light-Emitting Diodes Utilizing a BlueEmitting Electron-Transport Layer ACS Omega, 2018, 3, 12549−12553.

37.    Shigan Guo, Weibo Yan, Jianhua Chen, Chengcheng Tang, Zilong Wang, Jingjing Jiang, Hao Xin*Synthesis of star-shaped non-fullerene acceptors and their applications in organic solar cells,Synthetic Metals, 2018, 245, 167-174.

38.    Jiang, J. J.; Yu, S. T.; Gong, Y. C.; Yan, W. B.; Zhang, R.; Liu, S. J.; Huang, W. and Xin, H.*10.3% Efficient CuIn(S,Se)2 Solar Cells from DMF Molecular Solution with the Absorber Selenized under High Argon Pressure” Solar RRL, 2018, 1800044.

39.    Yan, W.; Rao, H.; Wei, C.; Liu, Z.; Bian, Z.; Xin, H.*; Huang, W*. “Highly efficient and stable inverted planar solar cells from (FAI)x(MABr)1−xPbI2 perovskites”; Nano Energy 2017, 35, 62-70.

40.     Xin, H.; Vorpahl, S. M.; Collord, A. D.; Braly, I. L.; Uhl, A. R.; Krueger, B. W.; Ginger, D. S. and Hillhouse, H. W. “Lithium-doping inverts the nanoscale electric field at the grain boundaries in Cu2ZnSn(S,Se)4 and increases photovoltaic efficiency,” Phys. Chem. Chem. Phys. 2015, 2015,17, 23859-23866.

41.    Xin, H.; Katahara, J. K.; Braly I. L. and Hillhouse, H. W. “8% Efficient Cu2ZnSn(S,Se)4 Solar Cells from Redox Equilibrated Simple Precursors in DMSO” Adv. Energy Mater. 2014, DOI10.1002/aenm.201301823.

42.    Collord, A. D.; Xin, H. and Hillhouse, H. W. “Combinatorial Exploration of the Effects of Intrinsic and Extrinsic Defects in Cu2ZnSn(S,Se)4”, IEEE J. Photovoltaics 2015, 5, 288-298.

43.    Salvador, M.; Vorpahl, S. M.; Xin, H.; Williamson, W.; Shao, G.; Karatay, D. U.; Hillhouse, H. W.;. Ginger. D. S. “Nanoscale Surface Potential Variation Correlates with Local S/Se Ratio in Solution-Processed CZTSSe Solar Cells,” Nano Lett. 2014, 14, 6926−6930.

44.    Subramaniyan, S,; Xin, H.; Kim, F. S.; Murari, N. M.; Courtright, B. A. E.; Jenekhe, S. A. “Thiazolothiazole Donor-Acceptor Conjugated Polymer Semiconductors for Photovoltaic Applications,”  Macromolecules, 2014, 47, 4199-4209.

45.    Xin, H. and Hillhouse, H. W. 8.3% Efficient Copper Zinc Tin Sulfoselenide Solar Cells Processed from Environmentally Benign Solvent,” Proceedings of 39th IEEE Photovoltaic Specialists Conference (PVSC) , 2013, 441-443.

46.    Shoaee, S.; Subramaniyan S.; Xin, H.; Keiderling, C.; Tuladhar, P. S.; Jamieson, F., Jenekhe, S. A.; Durrant, J. R. “Charge Photogeneration for a Series of Thiazolo-Thiazole Donor Polymers Blended with the Fullerene Electron Acceptors PCBM and ICBA,” Adv. Funct. Mater. 2013, 23, 3286-3298.

47.    Xin, H.; Guo, X.; Ren, G.; Watson, M. D.; Jenekhe, S. A. “Efficient Phthalimide Copolymer-Based Bulk Heterojunction Solar Cells: How the Processing Additive Influences Nanoscale Morphology and Photovoltaic Properties,” Adv. Energy Mater. 2012, 2, 575-582.

48.    Xin, H; Subramaniyan, S.; Kwon, T-W.; Shoaee, S.; Durrant, J. R; Jenekhe, S. A. “Enhanced Open Circuit Voltage and Efficiency of Donor-Acceptor Copolymer Solar Cells by Using Indene-C60 Bisadduct,” Chem. Mater. 2012, 24, 1995-2001.

49.    Hwang, Y. J.; Kim, F. S.; Xin, H.; Jenekhe, S. A. “New Thienothiadiazole-Based Conjugated Copolymers for Electronics and Optoelectronics,” Macromolecules 2012, 45, 3732-3739.

50.    Lee, H. J.; Xin, H.; Park, S. M.; Park, S. I.; Ahn, T.; Park, D. K.; Jenekhe, S. A.; Kwon, T. W. “Synthesis and Properties of Diarylamino-Substituted Linear and Dendritic Oligoquinolines for Organic Light-Emitting Diodes,” Bulletin Korean Chem. Soc. 2012, 33, 1627-1637.

51.    Subramaniyan, S.; Xin, H.; Kim, F. S.; Shoaee, S.; Durrant, J. R.; Jenekhe, S. A. “Effects of Side Chains on Thiazolothiazole-Based Copolymer Semiconductors for High Performance Solar Cells,” Adv. Energy Mater. 2011, 5, 854-860.  

52.    Guo, X.; Xin, H.; Kim, F. S.; Liyanage, A. D. T.; Jenekhe, S. A.; Watson, M. D. “Thieno[3,4-c]pyrrole-4,6-dione-Based Donor-Acceptor Conjugated Polymers for Solar Cells,” Macromolecules 2011, 44,: 269-277.

53.    Subramaniyan, S.; Xin, H.; Kim, F. S.; Jenekhe, S. A. “New Thiazolothiazole Copolymer Semiconductors for Highly Efficient Solar Cells,” Macromolecules 2011, 44, 6245-6248.

54.    Ahmed, E.; Subramaniyan, S.; Kim, F. S.; Xin, H.; Jenekhe, S. A. “Benzobisthiazole-Based Donor-Acceptor Copolymer Semiconductors for Photovoltaic Cells and Highly Stable Field-Effect Transistors,” Macromolecules, 2011, 44, 7207-7219. 

55.    Xin, H.; Reid, O. G.; Ren, G.; Kim, F. S.; Ginger, D. S.; Jenekhe, S. A. “Polymer Nanowire/Fullerene Bulk Heterojunction Solar Cells: How Nanostructure Determines Photovoltaic Properties,” ACS Nano, 2010, 4, 1861-1872.

56.    Reid, Obadiah G.; Xin, H.; Jenekhe, Samson A.; Ginger, David S. “Nanostructure determines the intensity-dependence of open-circuit voltage,” J. Appl. Phys. 2010, 108, 084320.

57.    Xin, H.; Guo, X. G.; Kim, F. S.; Ren, G.; Watson, M. D.; Jenekhe, S. A. “Efficient Solar Cells Based on a New phthalimide-based Donor-Acceptor Copolymer semiconductor: Morphology, Charge-Transport, and Photovoltaic Performance,” J. Mater. Chem. 2009, 19, 5303-5310.

58.    Wu, P-T; Xin, H.; Kim, F. S.; Ren, G.; Jenekhe, S. A. “Regioregular Poly(3-pentylthiophene): Synthesis, Self-Assembly of Nanowires, High-Mobility Field-Effect Transistors, and Efficient Photovoltaic Cells,” Macromolecule 2009, 42, 8817-8826.

59.    Ahmed, E.; Kim, F. S.; Xin, H.; Jenekhe, S. A. “Benzobisthiazole-Thiophene Copolymer Semiconductors: Synthesis, Enhanced Stability, Field-Effect Transistors, and Efficient Solar Cells,” Macromolecule 2009, 42, 8615-8618.

60.    Geng, F.; Matsushita, Y.; Ma, R.; Xin, H.; Tanaka, M.; Iyi, N.; Sasaki, T. “Synthesis and Properties of Well-Crystallized Layered Rare-Earth Hydroxide Nitrates from Homogeneous Precipitation,” Inorg. Chem. 2009, 48, 6724–6730.

61.    Xin, H.; Kim, F. S.; Jenekhe, S. A. “Highly efficient solar cells based on poly(3-butylthiophene) nanowires,” J. Am. Chem. Soc. 2008, 130, 5424-5425.  

62.    Xin, H.; Ren, G.; Kim, F. S.; Jenekhe, S. A. “Bulk Heterojunction Solar Cells from Poly(3-butylthiophene)/Fullerene Blends: In Situ Self-Assembly of Nanowires, Morphology, Charge Transport, and Photovoltaic Properties,” Chem. Mater. 2008, 20, 6199-6207. 

63.    Geng, F.; Xin, H. (first coauthor); Matsushita, Y.; Ma, R.; Tanaka, M.; Izumi, F.; Iyi, N.; Sasaki, T.  “New layered rare-earth hydroxides with anion-exchange properties,” Chem. Eur. J. 2008, 14, 9255-9260.

64.    Geng, F.; Matsushita, Y.; Ma, R.; Xin, H.; Tanaka, M.; Izumi, F.; Iyi, N.; Sasaki, T. “General Synthesis and Structural Evolution of a Layered Family of Ln8(OH)20Cl4nH2O (Ln = Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Y),” J. Am. Chem. Soc. 2008, 130, 16344-16350. 

65.    Xin, H.; Ebina, Y.; Ma, R.; Takada, K.; Sasaki, T. “Thermally stable luminescent composites fabricated by confining rare earth complexes in the two-dimensional gallery of titania nanosheets and their photophysical properties,” J. Phys. Chem. B. 2006, 110, 9863-9868.

66.    Xin, H.; Ma, R.; Wang, L.; Ebina, Y.; Takada, K.; Sasaki, T. “Photoluminescence Properties of Lamellar Aggregates of Titania Nanosheets Accommodating Rare Earth Ions,” Appl. Phys. Lett. 2004, 85, 4187-4189. 

67.    Xin, H.; Shi, M.; Gao, X. C.; Huang, Y. Y.; Gong, Z. L.; Nie, D. B.; Cao, H.; Bian, Z. Q.; Li, F. Y.; Huang, C. H. “The Effect of Different Neutral Ligands on Photoluminescence and electroluminescence Properties of Ternary Terbium Complexes,” J. Phys. Chem. B. 2004, 108, 10796-10800.

68.    Xin, H.; Sun, M.; Wang, K. Z.; Zhang, Y. A.; Jin, L. P.; Huang, C. H. “Voltage-independent pure red devices based on a carbazole-functionalized europium complex,” Chem. Phys. Lett. 2004, 388, 55-57.

69.    Bian, Z. Q.; Gao, D. Q.; Guan, M.; Xin, H.; Li, F. Y.; Huang, C. H.; Wang, K. Z.; Jin, L. P. “Electroluminescent properties of three ternary europium complexes with different phenanthroline derivatives,” Science in China Series B-Chem. 2004, 47, 326-334.

70.    Gao, D. Q.; Guan, M.; Xin, H.; Bian, Z. Q.; Huang, C. H. “Photoluminescent and electroluminescent properties of ligand emitting Y3+, La3+, Gd3+ and Lu3+ complexes,” J. Rare Earths 2004, 22, 206-209.

71.    Xin, H.; Li, F. Y.; Bian, Z. Q.; Huang, C. H. “Efficient Electroluminescence from a New Terbium Complex,” J. Am. Chem. Soc. 2003, 125, 7166-7167.

72.    Xin, H.; Shi, M.; Li, F. Y.; Zhang, X. M.; Bian, Z. Q.; Ibrahim, K.; Liu, F. Q.; Huang, C. H. “Carrier-Transport, Photoluminescence and Electroluminescence Properties Comparison of a Series Terbium Complex with Different Structure,” Chem. Mater. 2003, 15, 3728-3733.

73.    Xin, H.; Sun, M.; Wang, K. Z.; Zhang, Y. A.; Jin, L. P.; Guan, M.; Huang, C. H. “Carbazole-Functionalized Europium Complex and Its light-Emitting Properties,” J. Appl. Phys. 2003, 94, 4729-4731.

74.    Xin, H.; Shi, M.; Li, F. Y.; Gao, D. Q.; Huang, C. H. “Photoluminescence and Electroluminescence of Three Ternary Lutetium Complexes,” New J. Chem. 2003, 27, 1485-1489.

75.    Sun, M.; Xin, H.; Wang, K. Z.; Zhang, Y. A.; Jin, L. P.1.       Chunxu Xiang, Mingjun Yuan1, Chuanan Ding, Yuanyuan Zheng, Yize Li, Xiaole Hu, Jie Zhang, Xinyu Li, Chengfeng Ma, Shaoying Wang*, Weibo Yan, Chunlei Yang, Wei Huang*, Hao Xin* Solution-Processed Kesterite Solar Module with 10.1% Certified Efficiency, Nature Energy, 2025, DOI:10.1038/s41560-025-01860-3.

2.       Yuancai Gong, Qiang Zhu, Bingyan Li, Shanshan Wang, Biwen Duan, Licheng Lou, Chunxu Xiang, Erin Jedlicka, Rajiv Giridharagopal, Yage Zhou, Qi Dai, Weibo Yan, Shiyou Chen*, Qingbo Meng*, Hao Xin*, Elemental de-mixing-induced epitaxial kesterite/CdS interface enabling 13%-efficiency kesterite solar cells, Nature Energy, 2022, 7, 966–977.

3.       Licheng Lou, jinlin Wang, Yuan Li, Kang Yin, Xiao Xu, Bowen zhang, Menghan jiao, shudan chen, Tan Guo, jingchen Wang, Yiming Li, jiangjian shi*, Huijue Wu, Ruijuan Xiao, Hao Xin*, Yanhong Luo*, Dongmei Li, Qingbo Meng* Multi-interface engineering for all-solution-processed kesterite solar cells, Joule, 2025, DOI: 10.1016/j.joule.2025.102091.

4.       Aoqi Xu, Xinyu Li, Hongkun Liu, Chunxu Xiang, Chengfeng Ma, Yize Li, Xiangyu Pan, Weibo Yan, Shaoying Wang, Wei Huang, Hao Xin* Over 10% Efficiency Pure Sulfide Kesterite Solar Cells on Transparent Electrode with Cd-Ag Co-Alloying, Small, 2025, 21, 2407075.

5.       Yuanyuan Zheng, Chunxu Xiang, Yuancai Gong, Yize Li, Shiliang Xiao, Haoyu Guo, Chengfeng Ma, Shaoying Wang*, Weibo Yan*, Wei Huang, Hao Xin*, Effects of cadmium alloying on solution-processed CZTSSe solar cells: morphology, band alignment and efficiency improvement, Sci. China Mater. 2025, 68, 523-530.

6.       Hongzheng Dong, Xiangyu Pan, Yuancai Gong, Mengfan Xue, Pin Wang, SocMan Ho-Kimura, Yingfang Yao, Hao Xin*, Wenjun Luo*, Zhigang Zou, Potential window alignment regulating ion transfer in faradaic junctions for efficient photoelectrocatalysis. Nature Communications, 2023, 14: 7969.

7.       Xinyu Li, Chengfeng Ma, Naiyun Liu, Chunxu Xiang, Shuxia Wei, Weibo Yan, Wei Huang*, Hao Xin*, Back Contact Plasma Treatment Enables 14.5% Efficient Solution-Processed CuIn(S,Se)2 Solar Cells, Advanced Functional Materials, 2023, 2310124.

8.       Lisi Yang, Shuaishuai Shen, Xiang Chen, Huan Wei, Dongdong Xia*, Chaowei Zhao, Ningfang Zhang, Yuanyuan Hu, Weiwei Li, Hao Xin*, Jinsheng Song*, Doped/Undoped A1-A2 Typed Copolymers as ETLs for Highly Efficient Organic Solar Cells, Advanced Functional Materials, 2023, 2303603.

9.       Yage Zhou, Chunxu Xiang, Qi Dai, Sitong Xiang, Ran Li, Yuancai Gong, Qiang Zhu, Weibo Yan, Wei Huang*, Hao Xin*, 11.4% Efficiency Kesterite Solar Cells on Transparent Electrode, Advanced Energy Materials, 2023, 2300253.

10.    Jiazheng Zhou, Xiao Xu, Huijue Wu, Jinlin Wang, Licheng Lou, Kang Yin, Yuancai Gong, Jiangjian Shi, Yanhong Luo, Dongmei Li*, Hao Xin*, Qingbo Meng*, Control of the phase evolution of kesterite by tuning of the selenium partial pressure for solar cells with 13.8% certified efficiency, Nature Energy, 2023, 8, 526–535.

11.    Mingjun Yuan, Chunxu Xiang, Zhen Yan, Hongfei Zhou, Naiyun Liu, Shuxia Wei, Wei Li, Weibo Yan, Chunlei Yang*, Hao Xin*, 4.3% efficient kesterite solar cell modules, Science Bulletin, 2023, 68(14), 1497-1499.

12.    Xiangyu Pan, Xinyu Li, Yuntian Yang, Chunxu Xiang, Aoqi Xu, Hongkun Liu, Weibo Yan, Wei Huang*, Hao Xin*, 12.3% Efficient Low Voc Loss Pure Sulfide Kesterite Solar Cells from DMSO Solution via Cadmium Alloying, Advanced Energy Materials, 2023, 2301780.

13.    Yuancai Gong, Qiang Zhu, Bingyan Li, Shanshan Wang, Biwen Duan, Licheng Lou, Chunxu Xiang, Erin Jedlicka, Rajiv Giridharagopal, Yage Zhou, Qi Dai, Weibo Yan, Shiyou Chen*, Qingbo Meng*, Hao Xin*, Elemental de-mixing-induced epitaxial kesterite/CdS interface enabling 13%-efficiency kesterite solar cells, Nature Energy, 2022, 7, 966–977.

14.    Shaotang Yu; Bingyan Li; Jingjing Jiang; Xinge Liu; Shasha Hao; Shuaiqi Han; Weibo Yan*; Hao Xin*, Solution-Processed Chalcopyrite Solar Cells: the Grain Growth Mechanism and the Effects of Cu/In Mole Ratio, Advanced Energy Materials, 2022, 2103644.

15.    Jinlin Wang; Jiazheng Zhou; Xiao Xu; Fanqi Meng; Chunxu Xiang; Licheng Lou; Kang Yin; Biwen Duan; Huijue Wu; Jiangjian Shi; Yanhong Luo; Dongmei Li*; Hao Xin*; Qingbo Meng*, Ge-Bidirectional Diffusion to Simultaneously Engineer Back Interface and Bulk Defects in the Absorber for Efficient CZTSSe Solar Cells, Advanced Materials, 2022, 2202858.

16.    Yuancai Gong; Ruichan Qiu; Chuanyou Niu; Junjie Fu; Erin Jedlicka; Rajiv Giridharagopal; Qiang Zhu; Yage Zhou; Weibo Yan;Shaotang Yu; Jingjing Jiang; Sixin Wu*; David S. Ginger*; Wei Huang*; Hao Xin*; Ag Incorporation with Controlled Grain Growth Enables 12.5% Efficient Kesterite Solar Cell with Open Circuit Voltage Reached 64.2% Shockley-Queisser Limit, Advanced Functional Materials, 2021, 2101927.

17.    Yuancai Gong; Yifan Zhang; Qiang Zhu; Yage Zhou; Ruichan Qiu; Chuanyou Niu; Weibo Yan*; Wei Huang; Hao Xin*, Energy & Environmental Science, 2021, 14(4): 2369-2380.

18.    Yuancai Gong; Yifan Zhang; Erin Jedlicka; Rajiv Giridharagopal; James A. Clark; Weibo Yan; Chuanyou Niu; Ruichan Qiu; Jingjing Jiang; Shaotang Yu; Sanping Wu; Hugh W. Hillhouse; David S. Ginger; Wei Huang; Hao Xin*, Science China Materials,2021, 64(5): 1304-1304.

19.    Jiang, J. J.; Giridharagopal, R.; Jedlicka, E.; Sun, K. W.; Yu, S. T.; Wu, S. P.; Gong, Y. C.; Yan, W. B.; Ginger, D. S.;* Green, M. A.; Hao, X. J.;* Huang, W. and Xin, H.* “Highly Efficient Copper-Rich Chalcopyrite Solar Cells from DMF Molecular Solution” Nano Energy 2020, 69, 104438.

20.    Wu, S. P.; Jiang, J. J; Yu, S. T.; Gong, Y. C.; Yan, W. B.; Xin, H.* and Huang, W. “Over 12% efficient low-bandgap CuIn(S,Se)2 solar cells with the absorber processed from aqueous metal complexes solution in air” Nano Energy 2019, 62, 818-822.

21.    Xin, H.; Katahara, J. K.; Braly I. L. and Hillhouse, H. W. “8% Efficient Cu2ZnSn(S,Se)4 Solar Cells from Redox Equilibrated Simple Precursors in DMSO” Adv. Energy Mater. 2014, DOI10.1002/aenm.201301823.

22.    Xin, H.; Guo, X.; Ren, G.; Watson, M. D.; Jenekhe, S. A. “Efficient Phthalimide Copolymer-Based Bulk Heterojunction Solar Cells: How the Processing Additive Influences Nanoscale Morphology and Photovoltaic Properties,” Adv. Energy Mater. 2012, 2, 575-582.

23.    Xin, H; Subramaniyan, S.; Kwon, T-W.; Shoaee, S.; Durrant, J. R; Jenekhe, S. A. “Enhanced Open Circuit Voltage and Efficiency of Donor-Acceptor Copolymer Solar Cells by Using Indene-C60 Bisadduct,” Chem. Mater. 2012, 24, 1995-2001.

24.    Xin, H.; Reid, O. G.; Ren, G.; Kim, F. S.; Ginger, D. S.; Jenekhe, S. A. “Polymer Nanowire/Fullerene Bulk Heterojunction Solar Cells: How Nanostructure Determines Photovoltaic Properties,” ACS Nano, 2010, 4, 1861-1872.

25.    Xin, H.; Guo, X. G.; Kim, F. S.; Ren, G.; Watson, M. D.; Jenekhe, S. A. “Efficient Solar Cells Based on a New phthalimide-based Donor-Acceptor Copolymer semiconductor: Morphology, Charge-Transport, and Photovoltaic Performance,” J. Mater. Chem. 2009, 19, 5303-5310.

26.    Xin, H.; Kim, F. S.; Jenekhe, S. A. “Highly efficient solar cells based on poly(3-butylthiophene) nanowires,” J. Am. Chem. Soc. 2008, 130, 5424-5425.  

27.    Xin, H.; Ren, G.; Kim, F. S.; Jenekhe, S. A. “Bulk Heterojunction Solar Cells from Poly(3-butylthiophene)/Fullerene Blends: In Situ Self-Assembly of Nanowires, Morphology, Charge Transport, and Photovoltaic Properties,” Chem. Mater. 2008, 20, 6199-6207. 

28.    Xin, H.; Li, F. Y.; Bian, Z. Q.; Huang, C. H. “Efficient Electroluminescence from a New Terbium Complex,” J. Am. Chem. Soc. 2003, 125, 7166-7167.

29.    Xin, H.; Shi, M.; Li, F. Y.; Zhang, X. M.; Bian, Z. Q.; Ibrahim, K.; Liu, F. Q.; Huang, C. H. “Carrier-Transport, Photoluminescence and Electroluminescence Properties Comparison of a Series Terbium Complex with Different Structure,” Chem. Mater. 2003, 15, 3728-3733. 









指导的优秀研究生代表:

龚元才:2016-2022,以第一作者在Nature Energy,Energy & Environmental Science, Advanced Energy Materials, Science China Materials等国际知名期刊发表多篇研究论文,在校期间多次获国家级奖、校级奖学金,获南京邮电大学十大学术之星;毕业论文获江苏省优秀博士学位论文(2023);2022年去西班牙加泰罗尼亚理工大学进行博士后研究,2023年获玛丽居里奖学金。

潘翔宇:2021-2024,以第一作者在Nature Communications, Advanced Energy Materials 发表学术论文,在校期间多次获国家级奖、校级奖学金;在国际学术会议做口头报告;毕业论文入选(2024)中国电子学会激励计划;目前在南京大学攻读博士学位。